Dual initiator water-in-oil emulsion polymerization process

C - Chemistry – Metallurgy – 08 – F

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400/9003, 400/92

C08F 2/32 (2006.01) C08F 20/56 (2006.01)

Patent

CA 1248279

- 53 - ABSTRACT OF THE DISCLOSURE A process for the water-in-oil emulsion polymerization of at least one ethylenically-unsaturated monomer is disclosed wherein a water-in-oil emulsion of said monomer is polymerized in the presence of a first, highly reactive polymerization initiator until a small amount of polymer is present sufficiant to provide a shear-stable emulsion, followed by completing the polymerization in the presence of a second, less reactive polymerization initiator.

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