Dynamic halogenation of sorbents for the removal of mercury...

B - Operations – Transporting – 01 – D

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B01D 47/00 (2006.01) B01D 53/34 (2006.01) B01J 8/00 (2006.01)

Patent

CA 2557159

A halogen-containing gas is injected into a flowing transport air/sorbent stream at a point close to the point where the sorbent and transport air first mix to maximize the residence time available for the halogen-containing compound to be adsorbed onto the sorbent surface prior to the sorbent being injected into a flue gas containing mercury. This process maximizes the benefit and utilization of the halogen-containing reagent by placing it exactly where it is needed to facilitate elemental mercury removal - on the surface of the sorbent. The sorbent particles with their loading of adsorbed halogen-containing reagent enter the flue gas with a high reactivity for the removal of elemental mercury.

Selon l'invention, un gaz contenant de l'halogène est injecté dans un flux d'air de transport/sorbant, à un endroit proche de celui où le sorbant et l'air de transport se mélangent pour la première fois, de sorte à augmenter au maximum le temps de séjour pour le composé contenant de l'halogène à adsorber sur la surface du sorbant avant que ce dernier soit injecté dans un gaz de combustion contenant du mercure. Ce procédé permet de maximiser les bénéfices et l'utilisation du réactif contenant de l'halogène en le plaçant exactement là où il est nécessaire, afin de faciliter l'élimination de mercure élémentaire, sur la surface du sorbant. Les particules de sorbant, avec leur charge de réactif contenant de l'halogène adsorbé, pénètrent dans le gaz de combustion avec une réactivité élevée pour éliminer le mercure élémentaire.

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