Electrochemical detection system

G - Physics – 01 – N

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G01N 33/48 (2006.01) G01N 27/403 (2006.01) G01N 27/49 (2006.01) G01N 30/64 (2006.01) G01N 33/68 (2006.01) G01N 30/86 (2006.01)

Patent

CA 1195383

- 33 - ABSTRACT OF THE DISCLOSURE An improved apparatus for electrochemically analyzing a sample in solution is described. The apparatus comprises an electrochemical detector comprising a plurality of electrochemically isolated flow cells arranged in series so as to define at least one flow path. Each of the electrochemical flow cells in turn comprises at least one working electrode, at least one reference electrode, and at least one counter electrode. Electrical potentials are applied to the various working electrodes so that the sample solution is cyclically subjected to oxideation and reduction conditions whereby selected substances contained in the sample solution may be electrically screen or modified prior to detection and measurement on a downstream sensing electrode.

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