Electrochemical element with ceramic particles in the...

H - Electricity – 01 – M

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H01M 10/0562 (2010.01) H01M 10/052 (2010.01) H01M 4/36 (2006.01)

Patent

CA 2405746

A solid-stated rechargeable battery or other electrochemical element for use at high (> 40°C) temperature comprises a cathodic and/or anodic electrode comprising, as a host material for alkali metal ions, a normal or inverse spinel type material and an electrolyte layer sandwiched between said electrodes, which layer comprises ceramic electrolyte particles that are essentially free of electronically conductive components, and which comprise less that 1% by weight of dissolved alkali containing salt thereby maintaining good performance as regards the capacities delivered during various charge/discharge cycles at a high temperature.

L'invention concerne une batterie rechargeable à électrolyte solide ou un autre élément électrochimique pouvant être utilisé à une température élevée (> 40·C) et comprenant une électrode cathodique et/ou anodique renfermant, en tant que matière hôte pour les ions de métal alcalin, une matière de type spinelle normal ou inverse, une couche électrolytique étant prise en sandwich entre les électrodes. Cette couche comporte des particules électrolytiques céramiques sensiblement exemptes de composants électroniquement conducteurs et renfermant moins de 1 % en poids d'un sel contenant un alcali dissous, d'où la possibilité de conserver un rendement satisfaisant en termes de capacité fournie pendant plusieurs cycles de charge/décharge à une température élevée.

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