Electrochemical maintenance of optimum catalytic activity in...

Details Electrochemical maintenance of optimum catalytic activity in... Electrochemical maintenance of optimum catalytic activity in...

C - Chemistry, Metallurgy

25

B

204/53

C25B 3/00 (2006.01) B01J 23/94 (2006.01)

Patent

CA 1189821

ABSTRACT OF THE DISCLOSURE A process is provided for maintaining the activity of a copper-containing catalyst which is useful in producing amides from nitriles by hydrolysis. The copper-containing catalyst is utilized as at least one electrode of an electrochemical reactor containing a solution which comprises nitrile and water and wherein a direct current is applied to the reactor at least intermittently. The direct current is controlled to maintain at least a partial surface coverage of at least an average thickness of about 0.75 monolayers of ionic copper on the catalyst.

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