Electrochemical preparation of sodium and aluminum chloride

C - Chemistry – Metallurgy – 25 – C

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C25C 3/02 (2006.01)

Patent

CA 2228561

Proposed is an electrolytic method for the production of sodium and aluminium chloride in an electrolytic cell with an aluminium anode and a sodium cathode separated from each other by a sodium-ion- conducting solid electrolyte. In the anode region, molten electrolyte containing essentially sodium tetrachloroaluminate is electrolysed, the aluminium chloride produced being evaporated out of the cell and the sodium produced being tapped off from the cathode region.

L'invention concerne un procédé de production électrochimique de sodium et de chlorure d'aluminium. Dans une cellule d'électrolyse dotée d'une anode d'aluminium et d'une cathode de sodium, qui sont séparées par un électrolyte solide conduisant les ions de sodium, on électrolyse dans la zone de l'anode un électrolyte fondu contenant principalement du tétrachloroaluminate de sodium. Le chlorure d'aluminium ainsi produit est évaporé à l'extérieur de la cellule d'électrolyse et le sodium est retiré de la zone de la cathode.

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