Electrochemical process for decomposing hydrogen sulfide to...

C - Chemistry – Metallurgy – 25 – B

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C25B 1/02 (2006.01) C01B 3/06 (2006.01) C01B 17/04 (2006.01) C01B 17/06 (2006.01) C25B 1/00 (2006.01)

Patent

CA 2244560

A process is described for decomposing hydrogen sulfide to produce hydrogen and sulfur. The process comprises mixing hydrogen sulfide with a volatile basic solution and introducing this mixture into an electrolytic cell having an anode and a cathode. By operation of this cell, hydrogen is formed at the cathode and a solution containing polysulfide is formed at the anode. The polysulfide-containing solution is separated and distilled to recover sulfur and the remaining volatile basic solution is recycled to be mixed with further hydrogen sulfide.

Description d'une méthode pour décomposer l'hydrogène sulfuré en produisant de l'hydrogène et du soufre. La méthode consiste à mélanger l'hydrogène sulfuré avec une solution basique volatile, et à introduire le mélange obtenu dans une cellule électrolytique, munie d'une anode et d'une cathode. Cette cellule donne de l'hydrogène à la cathode et une solution contenant du polysulfure à l'anode. La solution renfermant le polysulfure est séparée et distillée pour récupérer le soufre; le reste de la solution basique volatile est recyclé pour être mélangé avec d'autre hydrogène sulfuré.

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