Electrochemical process for oxidation of alkanes to alkenes

C - Chemistry – Metallurgy – 25 – B

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C25B 3/02 (2006.01) C25B 5/00 (2006.01) H01M 4/86 (2006.01) H01M 4/92 (2006.01) H01M 8/00 (2006.01) H01M 8/04 (2006.01) H01M 8/10 (2006.01)

Patent

CA 2428200

An electrochemical process for the oxidation of an alkane to at least one corresponding alkene uses an electrochemical cell having an anode chamber on one side of a proton conducting medium, and a cathode chamber on the other side of the said medium. The alkane is oxidized in the anode chamber to produce at least one corresponding alkene and protons are transferred through a proton conducting membrane to the cathode chamber where protons combine with a proton acceptor, while generating electricity and water. An apparatus for use in the process is also provided.

L'invention concerne un procédé électrochimique pour oxyder un alcane en au moins un alcène correspondant, ce procédé faisant intervenir une cellule électrochimique comportant une chambre anodique sur une face d'un support conducteur de protons et une chambre cathodique sur l'autre face dudit support. L'alcane est oxydé dans la chambre anodique pour produire au moins un alcène correspondant, et les protons sont transférés à la chambre cathodique à travers une membrane conductrice de protons, chambre dans laquelle les protons se combinent à un accepteur de protons, générant ainsi de l'électricité et de l'eau. La présente invention porte également sur un appareil servant à la réalisation de ce procédé.

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