Electrochemical processing of aqueous solutions

C - Chemistry – Metallurgy – 25 – B

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C25B 1/26 (2006.01) C25B 1/10 (2006.01) C25B 15/08 (2006.01)

Patent

CA 2084183

The formation of sodium sulfate by-product in sulfuric acid-based chlorine dioxide generating processes is decreased and preferably eliminated entirely, by effecting electrochemical treatment of sodium ion-containing feed materials for the generator to remove sodium ions and to add hydrogen ions. Sodium hydroxide may be produced as a by-product. The process is generally applicable to the electrochemical treatment of alkali metal chlorates, alkali metal sulfates and mixtures thereof to produce acidified solutions useful in providing chlorate ion-containing feeds to such chlorine dioxide generating processes or for other purposes.

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