Electrochemical thermodynamo

H - Electricity – 01 – M

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H01M 4/86 (2006.01) C25B 1/12 (2006.01) H01M 8/04 (2006.01) H01M 8/18 (2006.01)

Patent

CA 2545114

Electrochemical cells modules made up of couples of catalytic multilayer porous electrodes forming the anodes and the cathodes and delimitating external gaseous areas and internal areas containing the electrolyte wherein the pressure modulators, generating two pressure cycles independently synchronized but of opposite phase, act at the inlet and at the outlet of the electrolyte and the multilayer porous electrodes are weeping on the gas side. According to a preferred embodiment the multilayer porous electrodes are hydrophobic and conductive on the gas side, the conductive and catalytic middle layers are hydrophobic and hydrophilic, the non-conductive and non- catalytic layer on the electrolyte side is hydrophilic. Furthermore, the present invention provides the electrochemical process using the above described electrochemical cell according to which the gas is maintained at a pressure P up to 200 bar, the electrolyte pressure is varied stepwise between P+dP and P+dp by generating on the electrolyte positive pressure waves of amplitude dP and dp at the frequency f.

La présente invention concerne des modules de cellules électrochimiques constituées de couples d'électrodes poreuses multicouches catalytiques formant les anodes et les cathodes et délimitant des zones gazeuses externes et des zones internes contenant l'électrolyte. En l'occurrence, les modulateurs de pression, générant deux cycles de pression synchronisés de façon indépendante, mais de phases opposées, agissent à l'entrée et à la sortie de l'électrolyte, les électrodes poreuses multicouches suintant côté gaz. Selon un mode de réalisation préféré, les électrodes poreuses multicouches sont hydrophobes et électro-conductrices du côté gaz, les couches médianes électro-conductrices et catalytiques étant hydrophobes et hydrophiles, la couche non-conductrice et non-catalytique du côté électrolyte étant hydrophile. L'invention concerne en outre le procédé électrochimique utilisant la cellule électrochimique décrite selon laquelle le gaz est conservé à une pression P pouvant atteindre 200 bar, la pression d'électrolyte variant par paliers entre P+dP et P+dp par génération sur l'électrolyte d'ondes de pression positives d'une amplitude dP et dp à la fréquence f.

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