Electroconductive powder and method for production thereof

H - Electricity – 01 – B

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H01B 5/00 (2006.01) C01G 23/04 (2006.01) H01B 1/20 (2006.01) H01B 13/00 (2006.01)

Patent

CA 2533371

A method for producing a titanium dioxide powder having a well electroconductive layer containing substantially no antimony, which comprises providing a titanium dioxide powder containing specific amounts or less of alkali metals, such as sodium and potassium, alkaline earth metals, such as magnesium and calcium, and metals having a valence of four or less, such as aluminum, zinc and iron, preparing an aqueous suspension of the titanium dioxide powder, adding an acidic aqueous solution containing a tin compound and a phosphorus compound and an alkaline solution to the above aqueous suspension so that the aqueous suspension has a pH in the range of 2 to 6 or 8 to 12, and firing the resulting product at a temperature of 600 to 925~C.

L'invention concerne un procédé destiné à produire une poudre de dioxyde de titane comprenant une couche fortement électroconductrice sensiblement exempte d'antimoine. Ce procédé consiste à utiliser une poudre de dioxyde de titane contenant des quantités spécifiques ou des quantités inférieures de métaux alcalins, tels que le magnésium et le calcium, ainsi que des métaux présentant une valence inférieure ou égale à 4, tels que l'aluminium, le zinc et le fer, à préparer une suspension aqueuse à partir de la poudre de dioxyde de titane, à ajouter une solution aqueuse acide contenant un composé d'étain et un composé de phosphore ainsi qu'une solution alcaline dans la suspension aqueuse susmentionnée de sorte que cette suspension aqueuse présente un pH compris entre 2 et 6 ou entre 8 et 12, puis à cuire le produit résultant à une température comprise entre 600 et 925 ·C.

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