Electrode with overlayer including oxides of platinum group,...

C - Chemistry – Metallurgy – 25 – B

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117/111, 204/195

C25B 11/06 (2006.01)

Patent

CA 1143699

Abstract of the Disclosure An electrode for electrochemical processes comprises an electrically conductive base topped with a layer of an active composition composed of, in wt %: metal oxide from the platinum group...5-45; at least one metal oxide from the iron and manganese group...19-94.9; boron oxide..Ø1-50. A method of fabricating the electrode for electrochemical processes involves the deposition of an active composition on an electrically conductive base. The procedure involves the application thereto of a solution made up of a boric compound, at least one metal compound from the iron and manganese group which decomposes at a temperature between 360 and 500°C to form oxides thereof, and at least one metal compound from the platinum group which decomposes at a temperature between 360 and 500°C to form oxides thereof, and thermal treatment of said base at a temperature of 360 to 500°C. Another method of fabricating the electrode for electrochemical processes involves the deposition of an active composition on an electrically conductive base by the application thereto of a first solution of a metal compound from the platinum group which decomposes at a temperature between 360 and 500°C to form oxides thereof; thermal treat- ment of said base at a temperature of 360 to 500°C, applica- tion thereto of a second solution made up of a boric compound which decomposes at a temperature between 360 and 500°C to form oxides thereof, and thermal treatment of said base at a temperature of 360 to 500°C.

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