Electrolytic hydrodimerization of acrylonitrile using a...

Details Electrolytic hydrodimerization of acrylonitrile using a... Electrolytic hydrodimerization of acrylonitrile using a...

C - Chemistry, Metallurgy

25

B

204/53.5

C25B 3/10 (2006.01)

Patent

CA 1051819

ABSTRACT OF THE DISCLOSURE In a process for hydrodimerizing an olefinic nitrile, amide or ester by electrolyzing an aqueous solution of the olefinic starting material, a conductive salt, where the for- mation of hydrogen at the cathode can be substantially inhi- bited and the current efficiency of the process significantly increased by including in the solution a nitrilocarboxylic acid compound such as a salt of ethylenediaminetetraacetic acid, there is provided the improvement of using quaternary phosphonium cations in the aqueous solution.

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