C - Chemistry – Metallurgy – 25 – B
Patent
C - Chemistry, Metallurgy
25
B
204/53.5
C25B 3/10 (2006.01)
Patent
CA 1039231
ELECTROLYTIC HYDRODIMERIZATION PROCESS IMPROVEMENT ABSTRACT OF THE DISCLOSURE In a process for hydrodimerizing an olefinic nitrile, amide or ester by electrolyzing an aqueous solution of the olefinic starting material, quaternary ammonium cations and a conductive salt, formation of hydro- gen at the cathode can be substantially inhibited and the current efficiency of the process can be thereby significantly increased by including in the solution a nitrilocarboxylic acid compound such as ethylenediaminetetra- acetic acid or a salt thereof. Particularly good results are obtained when the solution also contains a boric acid, a condensed phosphoric acid or an alkali metal or ammonium salt thereof. - 1 -
180193
Lester John H. (jr.)
Stewart James S.
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