Electrolytic hydrodimerization process improvement

C - Chemistry – Metallurgy – 25 – B

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204/53.5

C25B 3/10 (2006.01)

Patent

CA 1069851

ELECTROLYTIC HYDRODIMERIZATION PROCESS IMPROVEMENT ABSTRACT OF THE DISCLOSURE In a process for hydrodimerizing an olefinic nitrile, amide or ester by electrolyzing an aqueous solution of the olefinic starting material, conductive salt and a nitrilo- carboxylic acid compound that inhibits formation of hydrogen at the cathode, such hydrogen formation can be even further inhibited and the current efficiency of the process significantly further increased by including in the solution a tri(C2-C4 alkanol)amine such as triethanolamine.

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