Electrolytic preparation of perfluoroisopropylketocarboxylic...

C - Chemistry – Metallurgy – 25 – B

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204/52.3

C25B 3/00 (2006.01) C07C 45/00 (2006.01) C07C 59/21 (2006.01) C25B 3/02 (2006.01)

Patent

CA 1181358

-1- Abstract of disclosure: : perfluoroisopropylketocarboxylic acid fluorides I Image in which N = a number from 0 to 9, are prepared by electrolysis of the w-hydro-perfluoro-(2-methyl-alkan-3- ones) VI Image in which m = a number from 1 to 10, in fluorosulfonic acid/alkali metal fluorosulfonate and decomposition of the w-fluorosulfato-(2-methyl-alkan-3-ones) V thereby formed Image in which m has the above meaning, in the presence of catalytic amounts of an alkali metal fluoride and in the absence of polar aprotic solvents. The w- fluoro- (sulfato-(2-methyl-alkan-3-ones v are new compounds. The perfluoroisopropylketocarbozylic acid fluor- ides I are intermediates for the preparation of per- fluorinated ketocarboxylic acid esters which have an iso- propyl radical adjacent to the keto group and are in -2- turn, in particular, valuable heat transfer fluids and surfacc-active agents with a high stability to chemicals and heat.

385688

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