Electrowinning copper in hydrometallurgical process...

C - Chemistry – Metallurgy – 25 – C

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204/69.5

C25C 1/12 (2006.01) C22B 15/00 (2006.01) C25C 1/06 (2006.01)

Patent

CA 1246489

ELECTROWINNING COPPER IN HYDROMETALLURGICAL PROCESS INCLUDING A MEMBRANE CELL ABSTRACT OF THE DISCLOSURE This invention is directed to a novel hydro- metallurgical process for the recovery of copper and optionally, iron, from sulfide copper concentrates con- taining common copper sulfides such as chalcopyrite, bornite and chalcocite. A process for the recovery of copper utilizing electrowinning cells comprising leach- ing copper concentrate in first and second stages, the leaching in the first stage being done with a partially reduced leach liquor obtained from the second stage; separating the concentrate obtained from the first stage in a solid-liquid separator, the partially leached solids being directed to the second leaching stage, the liquid from the separator being directed to the catho- lyte compartment of an electrowinning cell; leaching the solids in the second leaching stage with regenerated leaching liquid obtained from the anolyte compartment of the electrowinning cell, the anolyte and catholyte com- partments being separated by a membrane which is impermeable to copper and iron ions but is permeable to hydrogen ions; separating the concentrate obtained from the second stage in a second solid-liquid separator and filtering and washing the solids residue from the separator.

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