Emulsion copolymer cation exchange resins and ion exchange...

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B01J 39/20 (2006.01) C02F 1/42 (2006.01)

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CA 1161597

ABSTRACT OF THE DISCLOSURE According to one aspect of the invention as disclosed, emulsion copolymer particles with diameters smaller than 1.5 micrometers and functionalized with cation exchange functional groups are prepared and suspended as emulsions in liquid media to form liquid cation exchange materials. Also, emulsion copolymer particles with diameters less than 1.5 micrometers are functionalized with anion exchange functional groups by a method involving coagulation of the emulsion, according to another aspect of the invention disclosed herein. Both weakly basic and strongly basic anion exchange resins are prepared from aromatic or acrylic copolymers, and the emulsion coagula may be resuspended to form anion exchange emulsion4. Additionally, by a further aspect of the invention as disclosed, ions are exchanged between emulsion ion exchange resins and conventional ion exchange resins during both batch and column contact. This process may be used to place the emulsion resin or the conventionai resin in the desired ionic form.

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