Emulsion polymer used as a packaging adhesive

C - Chemistry – Metallurgy – 08 – F

Patent

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Details

C08F 2/24 (2006.01) C08F 118/08 (2006.01) C08F 263/04 (2006.01) C09J 131/04 (2006.01)

Patent

CA 2196245

Emulsion adhesives which give high mileage in preparing corewound packaging are prepared by a semi-batch process which includes the steps of: a) charging the reactor with an aqueous solution of a colloidal stabilizer to which a mono-dispersed seed latex has been added, the seed latex having a volume average particle size of about 1.0-1.2 microns, and a population average particle size of about 0.7-0.8 microns as measured by Coulter Multisizing, and b) feeding a vinyl monomer and an initiator into the reactor over a period of about 3-4 hours such that the final polymer emulsion volume average is about 2.0-2.5 microns and a population average size of about 1.0-1.2 microns with a standard deviation of both of about 0.4-0.6 microns as measured by Coulter Multisizing.

Adhésifs en émulsion donnant un rendement élevé dans la préparation d'emballage sur mandrins, grâce à un procédé semi-continu, comprenant les étapes suivantes : a) chargement du réacteur avec une solution aqueuse d'un stabilisateur colloïdal auquel a été ajouté un latex germe mono-dispersé; les particules de latex ont une taille moyenne d'environ 1,0-1,2 micron, et une granulométrie moyenne d'environ 0,7-0,8 micron par la technique Coulter Multisizing; b) chargement du réacteur avec un monomère vinylique et un initiateur sur une période d'environ 3-4 heures, de telle façon que la taille finale moyenne de l'émulsion de polymère soit d'à peu près 2,0-2,5 microns, avec une granulométrie moyenne d'environ 1,0-1,2 micron et un écart-type d'à peu près 0,4-0,6 micron pour les deux selon la technique de mesure Coulter Multisizing.

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