Emulsion polymerization of vinyl chloride using mixed...

C - Chemistry – Metallurgy – 08 – F

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402/304, 402/357

C08F 2/24 (2006.01) C08F 14/06 (2006.01)

Patent

CA 1128696

ABSTRACT OF THE DISCLOSURE A one-step process for the emulsion polymerization of vinyl chloride using a water-soluble initiator and an aqueous emulsifier system of (1) a C12-C10 straight chain alkyl or alkenyl phosphate surfactant and (2) a C12-C20 straight chain alkyl or alkenyl alcohol and/or a straight chain saturated hydro- carbon having a carbon content of greater than 18 is disclosed. One suitable example of a straight chain phosphate surfactant is sodium lauryl phosphate. Suitable alcohols include stearyl alcohol, cetyl alcohol and eicosanol. A suitable hydrocarbon is eicosane. The resulting homo- and copolymer latices can be used in plastisols and organosols.

295512

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