Emulsion-polymerization process and electrically-conductive...

C - Chemistry – Metallurgy – 08 – G

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C08G 73/02 (2006.01) C08L 79/02 (2006.01) H01B 1/06 (2006.01) H01B 1/12 (2006.01)

Patent

CA 2204653

Emulsion-polymerization of electrically conductive polyaniline salts is disclosed. The process comprises combining water, a water-solubilizing organic solvent, an organic acid that is soluble in the organic solvent, an aniline monomer, and a radical initiator. An organic phase forms which contains the polyaniline salt of the organic acid wherein the organic phase is separable from an aqueous phase. The polyaniline salt so formed is soluble in organic carrier solvents at a concentration of 25 w/w % or greater.

On décrit la polymérisation en émulsion de sels de polyaniline électroconducteurs. Ce procédé consiste à combiner de l'eau, un solvant organique de solubilisation dans l'eau, un acide organique soluble dans le solvant organique, un monomère d'aniline ainsi qu'un initiateur radicalaire. Il se forme une phase organique qui contient le sel de polyaniline de l'acide organique, et que l'on peut séparer de la phase aqueuse. Le sel de polyaniline ainsi formé est soluble dans des solvants de support organiques à une concentration égale ou supérieure à 25 % en poids.

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