Enantiomerically pure hexahydropyrrolocyclopentapyridine...

C - Chemistry – Metallurgy – 07 – D

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C07D 471/04 (2006.01) A61K 31/437 (2006.01) A61P 25/28 (2006.01)

Patent

CA 2563575

The invention relates to the novel therapeutically valuable enantiomer-pure [3a.alpha.,8b.alpha.]-1,2,3,3a,4,8b-hexahydropyrrolocyclopentapyridine derivatives of the general formula (I), wherein Z is a single bond or CH2, R1 represents hydrogen or a straight-chain or branched, optionally unsaturated lower alkyl group which may be perfluorated, R2 and R3 independently represent hydrogen, a straight-chain or branched, optionally unsaturated lower alkyl group which may be perfluorated, lower alkoxy, lower alkylthio or halogen, and X and Y alternately represent CH or N. The invention also relates to the pharmaceutical salts thereof, to a method for their production and to their use.

L'invention concerne de nouveaux dérivés de [3a.alpha.,8b.alpha.]-1,2,3,3a,4,8b-hexahydro- pyrrolocyclopentapyridine exempts d'énantiomères ayant une valeur thérapeutique et la formule générale (I) où Z représente une liaison simple ou CH¿2? ; R1 représente un hydrogène ou un reste alkyle inférieur linéaire ou ramifié, éventuellement non saturé et pouvant également être perfluoré ; R2 et R3 représentent indépendamment l'un de l'autre hydrogène, un reste alkyle inférieur linéaire ou ramifié, éventuellement non saturé et pouvant également être perfluoré, un alcoxy inférieur, un alkylthio inférieur ou un halogène, X et Y représentent en alternance CH ou N. L'invention concerne également leurs sels pharmaceutiques, leur procédé de production et leur utilisation.

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