End-capping of polyarylate carboxyl acid ends by use of...

C - Chemistry – Metallurgy – 08 – G

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C08G 63/91 (2006.01) C08G 63/20 (2006.01) C08G 64/18 (2006.01) C08L 67/00 (2006.01) C08L 69/00 (2006.01)

Patent

CA 2004774

END-CAPPING OF POLYARYLATE CARBOXYL ENDS BY USE OF DIARYL OR POLYARYL CARBONATES ABSTRACT OF THE DISCLOSURE A process for improving the stability of polyarylate resin by reducing the terminal carboxyl acid group concentration of the polyarylate resin, the process being comprised of melting a mixture of the polyarylate resin and an aromatic carbonate capping agent and reacting the mixture under heat and, if necessary, vacuum until the concentration of the terminal carboxyl acid groups is reduced to less than that of the polyarylate resin prior to end-capping. The process also results in a polyarylate resin with a decreased flammability rating when the aromatic carbonate capping agent is bromine substituted.

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