End-functionalized polymers by controlled free-radical...

C - Chemistry – Metallurgy – 08 – F

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C08F 2/38 (2006.01) C08F 8/26 (2006.01)

Patent

CA 2306640

A controlled free-radical polymerization process for forming end- functionalized polymers is disclosed, particularly by degenerative iodine transfer. The end-functionalized polymers are characterized by a polydispersity less than 2.5 and a predetermined molecular weight. The end- functionalized polymers are useful as reactive intermediates in condensation polymerization, chain polymerization and heterogeneous polymerization reactions.

La présente invention concerne un procédé de polymérisation contrôlé radicalaire permettant de fabriquer des polymères à fonction terminale, notamment par transfert d'iode dégénérative. Les polymères à fonction terminale sont caractérisés par une polydispersité inférieure à 2,5 et un poids moléculaire prédéterminé. Les polymères à fonction terminale sont utilisés comme intermédiaires réactifs dans une polymérisation par condensation, une chaîne de polymérisation et des réactions de polymérisation hétérogènes.

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