Environmentally friendly autoxidisable alkyd coating...

C - Chemistry – Metallurgy – 08 – G

Patent

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C08G 63/49 (2006.01) C08G 18/42 (2006.01) C08G 69/44 (2006.01) C09D 167/08 (2006.01) C09D 175/06 (2006.01) C09D 177/12 (2006.01)

Patent

CA 2140589

An environmentally friendly autoxidisable alkyd coating composition (especially a paint) in which some of the film- forming material has been co-reacted with polyamide or a polyamine/polyisocyanate combination and which prior to the co-reaction has an Mz of at least 30,000, a viscosity of less than 34 stokes at 25°C measured as a 99wt% solution in xylene, a non-uniform molecular weight distribution which peaks in the range 1,500 to 3,500 which range also contains at least 25wt% of the material and preferably at least 2wt% of the material has a molecular weight above 100,000. This combination of characteristics enables the composition to contain less than 15wt% organic solvent if desired whilst retaining properties similar to conventional alkyd compositions. Preferred film-forming material contains esters of polycarboxylic acids containing at least three carboxylic acid groups in which the esterifying groups are a) alkyd polymer moieties, b) dipentaerythrityl and/or pentaerthrityl dicarboxylate moieties and optionally c) pentaerythrityl moieties.

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