Enzymatic racemate resolution of asymmetric alcohols

Details Enzymatic racemate resolution of asymmetric alcohols Enzymatic racemate resolution of asymmetric alcohols

C - Chemistry, Metallurgy

12

P

C12P 41/00 (2006.01) C12P 7/62 (2006.01)

Patent

CA 2115969

12 Abstract Process for enhancement of enantioselectivity in the enzymatic separation of (R)- and (S)-enantiomers of an asymmetric alkynol in the presence of a lipase and in the presence of at least one vinyl ester, in which the acid component has at least 4 C atoms, and if appropriate in the presence of an organic solvent and/or in the presence of water and a process for enhancement of enantioselectivity in the enzymatic separation of (R)- and (S)-enantiomers of an alcohol with the aid of the abovementioned vinyl ester under addition of a second vinyl ester having at least 2 C- atoms less in the alkyl chain than the vinyl ester used as esterifying agent.

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