Epipodophyllotoxin glucoside lactam derivatives

Details Epipodophyllotoxin glucoside lactam derivatives Epipodophyllotoxin glucoside lactam derivatives

C - Chemistry, Metallurgy

07

H

167/202, 260/228

C07H 15/26 (2006.01) A61K 31/70 (2006.01) C07H 17/00 (2006.01) C07H 17/04 (2006.01)

Patent

CA 1312329

ABSTRACT Novel antitumor epipodophyllotoxin glucoside lactam derivatives are prepared by first converting the lactone ring of the parent compound to the open-chain trans-hydroxy hydrazide, condensing the hydrazide with a carbonyl compound to form the corresponding hydrazone, and finally cyclizing the trans-hydroxy hydrazone using diethylazodicarboxylate and triphenylphosphine.

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