Epoxidation of ethylene

C - Chemistry – Metallurgy – 07 – D

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260/372.3

C07D 301/19 (2006.01) C07D 303/04 (2006.01)

Patent

CA 1231958

5493(2) ABSTRACT OF THE DISCLOSURE EPOXIDATION OF ETHYLENE A process for the selective epoxidation of ethylene to ethylene oxide comprises reacting ethylene with a hydroperoxide, for example tert-butyl hydroperoxide, in the presence of a complex formed from a Group VB or Group VIB metal and a bidentate, nitrogenous chelate ligand of general formula HO - Ar - CH = NR The reaction may be carried out optionally in the presence of an epoxide such as ethylene oxide or cyclohexene oxide.

450204

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