Epoxide isomerization process

Details Epoxide isomerization process Epoxide isomerization process

C - Chemistry, Metallurgy

07

C

260/629.2, 260/6

C07C 33/03 (2006.01) C07C 29/56 (2006.01) C07C 35/18 (2006.01)

Patent

CA 1223892

70474-143 ABSTRACT The present invention is directed to a process for the preparation of allylic alcohols by isomerizing an epoxide having at most two hydrogen atoms attached to the epoxy group in the presence of a metal alkoxide catalyst, characterised in that the catalyst is an alkoxide of a transition metal of Group IVB or VB of the Periodic Table of Elements, and the reaetion is carried out in the absence of a solvent. K 3423 FF

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