Epoxy alkoxy siloxane oligomers

C - Chemistry – Metallurgy – 08 – G

Patent

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Details

C08G 77/08 (2006.01) C08G 77/14 (2006.01) C08G 77/18 (2006.01) C08G 77/20 (2006.01) C08L 83/06 (2006.01)

Patent

CA 2398550

Polymerizable siloxane oligomers comprising a plurality of repeating units of formula (A) and at least one unit of formula (B) and terminating in a residue R2 or R8 are disclosed. In these formulae FG is a functional group, such as 2- (3,4-epoxycyclohexylethyl), and the R groups are alkyl, aryl, haloalkyl, aralkyl, alkoxy or aryloxy of 1 to 10 carbons. Processes for preparing the oligomers by hydrolysis/condensation of monomers of formula (RO)3Si FG and one or more alkoxy silane monomers of formula R3R4R8SiOR2a are also disclosed, as are polymers resulting from the cationic polymerization of the oligomers.

L'invention concerne des oligomères de siloxane polymérisables comprenant une pluralité d'unités récurrentes de formule (A) et au moins une unité de formule (B) et se terminant par un reste R?2¿ ou R?8¿. Dans ces formules, FG est un groupe fonctionnel tel que 2-(3,4-époxycyclohexyléthyle), et les groupes R représentent alkyle, aryle, haloalkyle, aralkyle, alcoxy ou aryloxy ayant 1 à 10 carbones. L'invention concerne également des procédés pour la préparation de ces oligomères par hydrolyse/condensation de monomères de formule (RO)¿3?SiFG et d'un ou de plusieurs monomères d'alcoxysilane de formule R?3¿R?4¿R?8¿SiOR?2a¿, ainsi que des polymères résultant de la polymérisation cationique de ces oligomères.

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