Ester production by hydrogenation of carboxylic acids and...

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252/84, 260/494.

B01J 21/06 (2006.01) C07C 67/00 (2006.01) C07C 67/08 (2006.01) C07C 69/14 (2006.01)

Patent

CA 2004753

Abstract of the Disclosure ESTER PRODUCTION BY HYDROGENATION OF CARBOXYLIC ACIDS AND ANYDRIDES A carboxylic acid ester is produced at a selectivity of greater than 50% whilst producing the corresponding alcohol at a selectivity less than 10% from a carboxylic acid or anhydride thereof by reacting the acid or anhydride with hydrogen at elevated temperature in the presence as catalyst of a composition comprising a component (i) comprising at least one of Group VIII noble metal and/or a component (ii) comprising at least one of molybdenum, tungsten and rhenium and a component (iii) comprising an oxide of a Group IVb element. The process is particularly applicable to the hydrogenation of acetic acid to ethyl acetate.

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