Ester-terminated polyamides of polymerized fatty acids...

C - Chemistry – Metallurgy – 08 – G

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C08G 63/02 (2006.01) A61K 8/88 (2006.01) A61Q 13/00 (2006.01) A61Q 17/00 (2006.01) A61Q 17/02 (2006.01) A61Q 17/04 (2006.01) A61Q 19/00 (2006.01) B01J 13/00 (2006.01) C08F 283/04 (2006.01) C08G 63/44 (2006.01) C08G 69/08 (2006.01) C08G 69/26 (2006.01) C08G 69/34 (2006.01) C08G 69/44 (2006.01) C08G 73/02 (2006.01) C08G 73/06 (2006.01) C08G 73/10 (2006.01) C08G 73/16 (2006.01) C11C 5/00 (2006.01) F23D 3/16 (2006.01)

Patent

CA 2268452

A low molecular weight, ester-terminated polyamide may be blended with a liquid hydrocarbon to form a transparent composition having gel consistency. The ester-terminated polyamide is prepared by reacting "x" equivalent of dicarboxylic acid wherein at least 50 % of those equivalents are from polymerized fatty acid, "y" equivalents of diamine such as ethylene diamine, and "z" equivalents of monoalcohol having at least 4 carbon atoms. The stoichiometry of the reaction mixture is such that 0.9 < {x/(y+z)} < 1.1 and 0.1 < {(y+z)} < 0.7. The reactants are heated until they reach reaction equilibrium. The gel contains about 5-50 % ester-terminated polyamide, with the remainder preferably being pure hydrocarbon. The gels are useful in formulating personal care products and other articles wherein some degree of gel-like or self-supporting consistency is desired.

Il est possible de mélanger un polyamide à terminaison ester, de faible poids moléculaire, à un hydrocarbure liquide en vue de la formation d'une composition transparente possédant la consistance d'un gel. On prépare ledit polyamide à terminaison ester en faisant réagir "x" équivalents d'acide dicarboxylique, 50 % au moins de ces équivalents provenant d'acide gras polymérisé, "y" équivalents de diamine du type éthylènediamine, et "z" équivalents de monoalcool possédant au moins 4 atomes de carbone. La stoechiométrie du mélange réactionnel satisfait les relations: 0,9 < [x/(y+z)] < 1,1 et 0,1 < [(y+z)] < 0,7. On chauffe les réactifs jusqu'à ce qu'ils atteignent l'équilibre réactionnel. Ledit gel (Fig.1) contient environ de 5 à 50 % de polyamide à terminaison ester, le reste étant de préférence constitué d'hydrocarbure pur. Ces gels sont utiles à la formulation de produits de soins personnels et d'autres articles qui doivent présenter, de préférence, une certaine consistance ou l'aspect d'un gel.

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