Ether phosphonate surfactants having branched hydrophobic...

C - Chemistry – Metallurgy – 07 – F

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31/28, 260/458.2

C07F 9/40 (2006.01) C09K 8/584 (2006.01) E21B 43/22 (2006.01)

Patent

CA 1315285

A B S T R A C T Novel ether phosphonate surfactants having a branched hydrophobic tail are used in a process for enhanced oil recovery from a subterranean oil reservoir. They combine a high oil-mobilizing capacity with a good tolerance against divalent ions. The ether phosphonate surfactants are summarized by the formula Image where R1 and R2, being the same or different, are hydrocarbons containing 3-18 carbon atoms each and optionally containing functional groups such as ether and hydroxyl; X is an alkyleneoxy group derived from an alkylene oxide having 2-3 carbon atoms; Y is an alkylene group having 1-4 carbon atoms; R3 is an alkyl group having 1-4 carbon atoms; M+ is a monovalent cation; n1 and n2, being the same or different, are a number from 0 to 4; m1 and m2, being the same or different, are 0 or 1, both m1 and m2 not being 0 at the same time and ml being 1 when n1 is a number from 1 to 4 and m2 always being 1 when n2 is a number from 1 to 4; and p is a number from 0 to 10.

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