Ethylene interpolymer polymerizations

Details Ethylene interpolymer polymerizations Ethylene interpolymer polymerizations

C - Chemistry, Metallurgy

08

F

C08F 10/02 (2006.01) C08F 10/00 (2006.01) C08F 297/08 (2006.01) C08L 23/08 (2006.01) C08F 4/659 (2006.01) C08F 4/6592 (2006.01)

Patent

CA 2125780

A new process of interpolymerizing ethylene interpolymer products having improved properties, such as increased onset of crystallization temperature, is disclosed. Preferably, the process comprises interpolymerizing a first homogeneous ethylene/alpha-olephin interpolymer and at least one second homogeneous ethylene/alpha-olephin interpolymer using at least two constrained geometry catalysts having different reactivities such that the first ethylene/alpha-olephin interpolymer has a narrow molecular weight distribution (NMWD) with a very high comonomer content and relatively high molecular weight and the second ethylene/alpha-olefin interpolymer has a NMWD with a low comonomer content and a molecular weight lower than that of the first interpolymer. The resultant first homogeneous interpolymer is combined with the resultant second homogeneous interpolymer in appropriate weight ratios resulting in the desired finished polymer structure. The first interpolymer and the second interpolymer can be polymerized in a single reactor or they can be polymerized in separate reactors operated in parallel or series.

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