C - Chemistry – Metallurgy – 08 – F
Patent
C - Chemistry, Metallurgy
08
F
C08F 10/02 (2006.01) C08F 4/69 (2006.01)
Patent
CA 2097365
A process to produce a polyethylene composition that has less than 2 weight percent fines, based on the weight of said polyethylene composition, and a fluff bulk density greater than 25 pounds per cubic foot, said process comprising polymerizing ethylene in the presence of a trialkylaluminum compound, and a diluent that is essentially saturated with ethylene under slurry polymerization conditions that comprise a polymerization temperature from 104°C to 116°C, with an activated catalyst system comprising (a) a catalyst support that comprises a silica compound, wherein said catalyst support has a pore volume less than 2 cubic centimeters per gram, (b) a catalyst that comprises a chromium compound, wherein the amount of chromium in said catalyst system is from about 0.1 to about 20 weight percent, wherein said weight percent is based on the total weight of said catalyst and catalyst support, and (c) a fluorine compound, wherein the amount of fluorine used is from about 0.1 to about 20 weight percent, wherein said weight percent is based on the total weight of said catalyst support.
Benham Elizabeth Ann
Mcdaniel Max Paul
Osler Hoskin & Harcourt Llp
Phillips Petroleum Company
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