Expanded and extruded thermoplastic foams made with methyl...

C - Chemistry – Metallurgy – 08 – J

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C08J 9/14 (2006.01) C08J 9/00 (2006.01)

Patent

CA 2579366

Low density expanded and extruded thermoplastic polymer foams are obtained using an environmentally benign non-VOC and non-HAP methyl formate as a blowing agent. The blowing agent can be a blend further including at least one co-blowing agent, preferably an environmentally friendly species (e.g., non- VOC and/or non-HAP). The co-blowing agent is either a physical co-blowing agent (e.g. an inorganic agent, a hydrocarbon, a halogenated hydrocarbon, a hydrocarbon with polar, functional group(s), water or any combination thereof), or a chemical co-blowing agent, or combinations thereof. The thermoplastic polymer foam can be an alkenyl aromatic polymer foam, e.g. a polystyrene foam. The blowing agent blend can include any combination of methyl formate and one or more co-blowing agents. The methyl formate-based blowing agent blends produce stable foams for various applications, including containers, packaging systems, as well as insulation boards and building materials. Processes for the preparation of such foams are also provided.

Mousses de polymère thermoplastiques expansées et extrudées faible densité obtenues au moyen d'un formate de méthyle non HAP et non VOC respectueux de l'environnement tenant lieu d'agent de soufflage. Ce dernier peut être un mélange comprenant au moins un agent de cosoufflage, de préférence une espèce respectueuse de l'environnement (p.ex. non VOC et/ou non HAP). L'agent de cosoufflage est soit un agent de cosoufflage physique (p.ex. un agent inorganique, un hydrocarbone, un hydrocarbone halogéné, un hydrocarbone à groupe(s) polaire(s) et fonctionnel(s), de l'eau ou une quelconque combinaison de ces éléments, soit un agent de cosoufflage chimique, ou leurs combinaisons. La mousse de polymère thermoplastique peut être une mousse de polymère aromatique alcényle, notamment une mousse de polystyrène. Le mélange d'agent de soufflage peut comporter une combinaison quelconque de formate de méthyle et un ou plusieurs agents de cosoufflage. Les mélanges d'agent de soufflage utilisant un formate de méthyle produisent des mousses stables trouvant différentes applications, à savoir dans des conteneurs, dans des systèmes d'emballage, ainsi que sur des panneaux isolants et des matériaux de construction. Procédés de préparation de telles mousses.

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