Fischer-tropsch processes and catalysts using fluorided...

C - Chemistry – Metallurgy – 07 – C

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C07C 27/00 (2006.01) B01J 23/889 (2006.01) B01J 27/12 (2006.01) B01J 27/125 (2006.01) B01J 27/128 (2006.01) B01J 37/02 (2006.01) C07C 1/04 (2006.01) C10G 2/00 (2006.01)

Patent

CA 2333171

A process is disclosed for producing hydrocarbons. The process involves contacting a feed stream comprising hydrogen and carbon monoxide with a catalyst in a reaction zone maintained at conversion-promoting conditions effective to produce an effluent stream comprising hydrocarbons. In accordance with this invention the catalyst used in the process includes at least one catalytic metal selected for Fischer-Tropsch reactions (e.g., iron, cobalt, nickel and/or ruthenium); and a support selected from the group consisting of fluorides and fluorided oxides of at least one element selected from the elements of Groups 2 through 15 of the periodic table of elements and elements with atomic numbers 58 through 71 (e.g., zinc, magnesium, calcium, barium, chromium, yttrium, lanthanum, samarium, europium and/or dysprosium).

L'invention concerne un procédé de production d'hydrocarbures. Le procédé consiste à mettre en contact un courant d'alimentation comprenant de l'hydrogène et du monoxyde de carbone avec un catalyseur dans une zone de réaction maintenue dans des conditions favorisant la conversion et efficaces pour produire un courant effluent comprenant des hydrocarbures. Selon cette invention, le catalyseur utilisé dans le procédé comprend au moins un métal catalytique sélectionné pour permettre des réactions Fischer-Tropsch (par exemple, du fer, du cobalt, du nickel et/ou du ruthénium); et un support sélectionné dans le groupe comprenant des fluorures et des oxydes fluorurés d'au moins un élément choisi parmi les éléments des groupes 2 à 15 de la table périodique des éléments et des éléments présentant des numéros atomiques de 58 à 71 (par exemple, le zinc, le magnésium, le calcium, le barium, le chrome, l'yttrium, le lanthane, le samarium, l'europium et/ou le dysprosium).

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