Flame-retardant, vapor-permeable waterproof structure

C - Chemistry – Metallurgy – 08 – L

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C08L 67/02 (2006.01) B32B 25/04 (2006.01) B32B 27/36 (2006.01) C08K 5/06 (2006.01) C08K 5/34 (2006.01) C08K 5/3417 (2006.01)

Patent

CA 1319802

ABSTRACT OF THE DISCLOSURE Title Flame-Retardant. Vapor-Permeable Waterproof Structure A flame resistant copolyetherester elastomer film composition comprising (a) 60-85 weight percent of a hydrophilic copolyetherester elastomer film having a thickness of 0.3-1.6 mils, a water vapor transmission rate of at least 7,000 gm.mil/m2/24 hours and an elongation of at least 600% with said hydrophilic elastomer film consisting essentially of a multiplicity of long chain ester units and short chain ester units joined head-to-tail through ester linkages, said long chain ester units being represented by the formula Image and said short chain ester units represented by the formula Image where G is a divalent radical remaining after the removal of terminal hydroxyl groups from a poly(alkylene oxide)glycol having an average molecular weight of about 400-3500 and, further, the poly(alkylene oxide)glycol contains sufficient units of ethylene oxide to incorporate in the resulting copolyetherester from about 25-68 weight percent units of ethylene oxide based on the total weight of the copolyetherester elastomer; R is a divalent radical remaining after the removal of carboxyl groups from a dicarboxylic acid having a molecular weight less than 300; D is a divalent radical remaining after the removal of hydroxyl groups from a diol having a molecular weight less than 250; the copolyetherester elastomer contains about 25-80 weight percent short chain ester units, and (b) 15-40 weight percent of a flame retardant component comprised of 37.5 to 100 weight percent of at least one brominated aromatic compound selected from the group consisting of tetradecabromodiphenoxybenzene, ethylenebistetrabromophthalimide, and decabromodiphenoxybenzene, wherein the ratio of the thickness of the hydrophilic copolyetherester film to the weight percent, as based upon the weight of components (a) and (b), of the brominated aromatic compound is less than 0.04. The flame retardant compound may be further comprised of no more than 62.5 weight percent of at least one compound selected from the group consisting of metal oxides, tricresyl- phosphate, aluminum trihydrate, and zinc borate.

609851

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