Fluorinated alkylamidoalkane sulfonic acids, process for...

C - Chemistry – Metallurgy – 11 – D

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C11D 1/12 (2006.01) B01F 17/10 (2006.01) B01F 17/22 (2006.01) B01F 17/26 (2006.01) C07D 213/26 (2006.01) C07D 213/40 (2006.01) C09K 3/00 (2006.01) D06P 1/62 (2006.01) C11D 1/14 (2006.01)

Patent

CA 1089465

Abstract of the Disclosure The invention is directed to fluorinated alkylamidoalkane sulfonic acids and salts of the formula Image , wherein Rf is straight or branched chain perfluoroalkyl of 1 to 18 carbon atoms or perfluoroalkyl substituted by perfluoroalkoxy of 2 to 6 carbon atoms, R1 is hydrogen or lower alkyl and R2, R4 and R5 are independently hydrogen or alkyl, and R6 is alkylene, alkylenethioalkylene, alkyleneoxyalkylene or alkylene- iminoalkylene with a secondary or tertiary nitrogen atom. R3 is hydrogen, alkyl, aryl or pyridyl, M is hydrogen, an alkali metal, an alkaline earth metal, a group derived from an organic base or ammonium, and n is an integer corresponding to the valency of M. Said compounds are prepared by a base catalyzed additon reaction of the thiol, Rf-R6SH, to an alkenylamidoalkane sulfonic acid salt. She compounds are useful as surfactants and as levelling agents in floor polish formulations.

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