Fluorinated transition metal catalysts and formation thereof

C - Chemistry – Metallurgy – 08 – F

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C08F 10/00 (2006.01)

Patent

CA 2647232

Supported catalyst systems and methods of forming polymers are generally described herein. The polymerization processes generally include contacting an inorganic support composition with a fluorinating agent to form a fluorinated support, wherein the fluorinating agent includes an organofluorine compound having the formula R4 nAlF3-n and wherein each R is independently selected from alkyls, aryls and combinations thereof and n is 1 or 2, contacting the fluorinated support with a transition metal compound to form a supported catalyst system and contacting an olefin monomer with the supported catalyst composition to form a polyolefin.

L'invention concerne de manière générale des systèmes de catalyseurs sur support et des procédés de formation de polymères. Les procédés de polymérisation comprennent de manière générale les étapes consistant à: mettre en contact une composition de support inorganique avec un agent fluorant pour former un support fluoré, l'agent fluorant comprenant un composé organofluoré représenté par la formule R4 nAlF3 - n dans laquelle chaque R est sélectionné indépendamment dans le groupe comprenant les alkyles, les aryles et des combinaisons de ceux-ci, et n égale 1 ou 2; mettre en contact le support fluoré avec un composé de métal de transition pour former un système de catalyseur sur support; et mettre en contact un monomère d'oléfine avec la composition de catalyseur sur support pour former une polyoléfine.

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