Fluoro prostacyclins

C - Chemistry – Metallurgy – 07 – D

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260/235.01

C07D 307/935 (2006.01) C07D 307/937 (2006.01) C07F 7/18 (2006.01)

Patent

CA 1208634

ABSTRACT Compounds of the formula Image I wherein one of the double bonds indicated by broken lines is present in 4,5 or 5,6-position, R is hydrogen or lower alkyl, R1 is methyl, hydrogen or hydroxy; R2 is hydrogen, methyl or fluoro; and R21 is hydrogen, fluoro, trifluoromethyl or methyl; with the proviso that when R21 is trifluoromethyl, R2 is hydrogen or methyl, their pharmaceutically acceptable salts, optical anti- podes or racemates are useful as anti-secretory agents, anti-hype-tensives, anti-ulcerogenic agents and blood platelet aggregation inhibiting agents. They can be prepared from compounds of the formula Image II

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