Formation of beryllium containing metallic glasses

C - Chemistry – Metallurgy – 22 – C

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C22C 9/00 (2006.01) C22C 25/00 (2006.01) C22C 45/10 (2006.01)

Patent

CA 2159618

Alloys which form metallic glass upon cooling below the glass transition temperature at a rate appreciably less than 106 K/s comprise beryllium in the range of from 2 to 47 atomic percent and at least one early transition metal in the range of from 30 to 75 % and at least one late transition metal in the range of from 5 to 62 %. A preferred group of metallic glass alloys has the formula: (Zr1-x Tix)a(CuI-yNiy)bBec- Generally, a is in the range from 30 to 75 % and the lower limit increases with increasing x. When x is in the range of from 0 to 0.15, b is in the range of from 5 to 62 %, and c is in the range of from 6 to 47 %. The value of c lies between 2 to 47 % depending on correlated value ranges for x and b within the broad range 0 < x < 1, and the corresponding b in the range of from 5 to 62 %. Figures 3-5 show quasi-ternary composition diagrams indicating in heavy lines the bracketed glass forming region of alloys. Other elements may also be present in the alloys in varying proportions

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