Functional polyorganosiloxane emulsions from dihydrolyzable...

C - Chemistry – Metallurgy – 09 – D

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C09D 5/32 (2006.01) B05D 3/06 (2006.01) C08G 77/20 (2006.01) C08G 77/26 (2006.01) C08G 77/28 (2006.01) C08L 83/04 (2006.01) C09D 183/04 (2006.01)

Patent

CA 2152763

A non-crosslinked polymer, comprising a preformed aqueous emulsion having a plurality of silanol-terminated polydiorganosiloxane particles, a functionalizing silane having the formula RQSi(X)2 where X is a hydrolyzable group, Q is an organic functional group which does not prevent a condensation reaction between X and a silanol-terminated polydiorganosiloxane molecule, R is Q or a saturated monovalent hydrocarbon group of from one to six carbon atoms and an organotin catalyst. The composition results in a non-crosslinked polymer, unlike the polymers described in the prior art. We have found that adding a functionalizing silane having only two hydrolyzable groups to a preformed polydiorganosiloxane emulsion results in functionalized polydiorganosiloxane molecules which are free of crosslinks between the polydiorganosiloxane chains.

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