Functionalized peroxides for polymerization reactions

C - Chemistry – Metallurgy – 07 – C

Patent

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C07C 409/38 (2006.01) C07C 409/00 (2006.01) C07C 409/40 (2006.01) C07C 409/42 (2006.01) C07D 209/48 (2006.01) C07D 303/44 (2006.01) C08F 283/00 (2006.01) C08F 291/00 (2006.01) C08F 293/00 (2006.01) C08G 18/86 (2006.01)

Patent

CA 2049451

Abstract of the Disclosure Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: Image R1, R2, R3, R4, R5, R6, R7, X, Y1, Y2, Y3, Z1 Z2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.

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