Gamma-undecenolactone, method for the preparation and use...

C - Chemistry – Metallurgy – 07 – D

Patent

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Details

C07D 307/32 (2006.01) A23L 1/23 (2006.01) A61K 8/49 (2006.01) A61Q 13/00 (2006.01) A61Q 15/00 (2006.01) C12P 17/04 (2006.01)

Patent

CA 2586953

The invention relates to a gamma-undecenolactone of formula (i), wherein a lactonic cycle can carry an unsaturation between carbon N°2 and carbon N°3 and is preferably saturated, RI is a possibly substituted C7 alkenyl or alkynyl group comprising at least one unsaturation, and preferably RI is an CH2=CH-CH2-CH2-CH2-CH2-CH2 group, said gamma-undecenolactone contains an asymetric carbon in position 4 having (R) or (S) configuration. The biosynthesis of said gamma-undecenolactone and the use thereon for perfumery and for a food flavouring agent are also disclosed.

Gamma-undécénolactone répondant à la formule (I) dans laquelle le cycle lactonique peut porter une insaturation entre le carbone N~2 et le carbone N~3 et est de préférence saturé et dans laquelle Rl est un groupe alcényle ou alcynyle en C7 portant au moins une insaturation, éventuellement substitué et de préférence Rl est le groupe CH2=CH-CH2-CH2-CH2-CH2-CH2, ladite gamma- undécénolactone présentant un carbone asymétrique en position 4 et pouvant être de configuration (R) ou (S) , biosynthèse de ladite gamma- undécénolactone, et utilisation en parfumerie et en aromatique alimentaire.

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