Gas separations using membranes comprising perfluorinated...

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B01D 53/22 (2006.01) B01D 71/32 (2006.01) C08J 5/22 (2006.01)

Patent

CA 1302303

ABSTRACT The invention is a method of separating a gas comprising helium, oxygen, nitrogen or carbon dioxide from a mixture of gases containing helium, oxygen, nitrogen light hydrocarbons or carbon dixoide wherein the method comprises A. contacting the gas mixture with a thin, non-porous membrane comprising a polymer with a perfluorinated backbone and pendant ionomer moieties which contain cations of alkali metals, alkaline earth metals, or transition metals under conditions such that helium, oxygen, nitrogen or carbon dioxide selectively permeates through the membrane to the other side of the membrane; and, 32,860-F B. removing the permeated helium, oxygen, nitrogen or carbon dioxide from the other side of the membrane. The membranes useful in the method of this invention demonstrate good selectivity for oxygen, helium, nitrogen and carbon dioxide over other gases in gas mixtures containing such gases. Furthermore, the permeabilities of oxygen, helium, and carbon dioxide through these membranes is quite good. 32,860-F

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