Glutarate containing polyesterpolyols and polyurethane...

C - Chemistry – Metallurgy – 08 – G

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400/106, 402/131

C08G 18/34 (2006.01) C07C 125/06 (1980.01)

Patent

CA 1093571

ABSTRACT OF THE DISCLOSURE Glutarate-containing polyesterpolyols are produced by reaction of primary and/or secondary diols and/or polyols with dimethyl glutarate in the presence of a transesterifacation catalyst which does not have deleteri- ous effects on the behavior of such polyesterpolyols when they are employed in the subsequent preparation of poly- urethane compositions, nor on the properties of such derived polyurethane compositions. The ratios of reac- tants are controlled so as to obtain essentially complete conversion to hydroxyl terminated compositions of pre- determined molecular weight and hydroxyl functionality. An important modification of the above polyesterpolyols is that in which they are subsequently used as polyol intermediates in the preparation of glutarate-containing co-polyesters. These hydroxyl terminated glutarate polyesters and co-polyesters are used to produce a wide variety of polyurethane compositions which exhibit unexpected and extremely useful combinations of properties. The polyurethane compositions are useful us elastomers, foams, coatings, adhesives, thermoplastics, plasticizers, etc.

300418

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