Granular activated carbon manufacture from brown coal...

B - Operations – Transporting – 01 – J

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B01J 21/18 (2006.01) C01B 31/14 (2006.01)

Patent

CA 1116155

AC1-4 GRANULAR ACTIVATED CARBON MANUFACTURE FROM BROWN COAL TREATED WITH DILUTE INORGANIC ACID Abstract of the Disclosure Granular activated carbon is manufactured from briquette of about 1" x 2", formed from brown coal, from which iron material has been extracted and which has a moisture content of about 15% by weight, by crushing and screening the pre- treated coal briquettes to produce 8/30 mesh granules, treating the granules with a dilute aqueous solution of inorganic acid (H2SO4, H3PO4 or HCl) at a concentration of about 1 to about 10% by weight to reduce the volatile content and thereby increase the fixed carbon content comprising: mixing the granules with the acid, washing off the acid, and drying the granules at least partially to a moisture content below about 25% by weight. In one case the washed granules are dried pertially to a moisture content of about 10 to about 25% by weight without the addition of a carbonaceous binder such as coal tar pitch. In the other case the granules are dried thoroughly and mixed with about 5 to about 15% by weight of coal tar pitch. The so treated granules are ground to form fine powder of more than about 65% by weight -325 mesh, more preferably 75 to 85% by weight -325 mesh, which is compressed into shapes such as pellets of 0.5" diameter and 0.5" long under a pressure of 40,000 to 80,000 psi, and then granulated to obtain 6/20 mesh granules. These reformed granules are devolatilized, without charring, by directly heating to and at a temperature higher than the charring temperature in an oxygen-free atmosphere, and then activated by heating to and at a temperature higher than the devola- tilizing temperature in an atmosphere containing a gaseous activating agent. The overall yield of granular activated - 1 - carbon is not less than about 22% by weight, dry basis, and the activated granules have a surface area of not less than about 900 m2/gram, an Iodine number of not less than about 900, an ash content of not more than about 7% by weight, an abrasion number of not less than about 70, an apparent density of not less than about 0.46 gram/cc, and a Molasses number of not less than about 200; which properties make them suitable for use in water and waste water treatment and in other applications.

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