Halide electrolysis in cell with catalytic electrode bonded...

C - Chemistry – Metallurgy – 25 – B

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204/57.3

C25B 1/46 (2006.01) C25B 9/10 (2006.01)

Patent

CA 1179630

52-EE-O-272 ABSTRACT OF THE DISCLOSURE A halogen, such as chlorine, is generated in an electrolysis cell in which at least one of the cell electrodes is bonded to the surface of a solid but porous membrance which separates the cell into anode and cathode chambers. A pressurized aqueous metal halide such as brine is electrolyzed at the anode to produce chlorine. Brine anolyte and sodium ions are hydraulic- ally transported across the porous membrane to produce caustic soda (NaOH) at the cathode. By bonding at least one gas-permeable, poroud electrode to the hydraulically- permeable membrane, the cell voltage for electrolysis of brine is considerably lower than that required for asbestos disphragm cells, while achieving high cathodic current efficiencies by minimizing back migration of caustic soda to the anode.

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