Haloorganometallic lithium salt complex compositions and...

C - Chemistry – Metallurgy – 07 – F

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C07F 3/00 (2006.01) C07F 5/02 (2006.01) C07F 5/06 (2006.01) C07F 9/02 (2006.01) H01M 6/14 (2006.01) H01M 10/40 (2006.01) H01M 6/16 (2006.01)

Patent

CA 1111859

ABSTRACT OF THE DISCLOSURE Novel compositions are described which comprises halogenated organometallic lithium salt complexes having the formula LiMRnXi wherein M is a metal selected from the group containing of Zn, Cd, B, Al, Ca, In, Tl, Sn (stannous), P and As, the Rs are specified haloorganic radicals, the Xs are selected from various halides, alkyls, aryls, alkaryls and aralkyls, and n and i are numerical values, the sum of which is equal to one plus the valence of the metal M, subject to the provisos that if n is zero, at least one X is an organic radical and that if i is zero, not all R radicals are perhalogenated aryl radicals. Also described are electrolyte compositions for electrochemical cells which contain electrolytically active lithium salt complexes including these novel compositions of matter.

319055

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